全文获取类型
收费全文 | 68864篇 |
免费 | 6721篇 |
国内免费 | 4270篇 |
专业分类
电工技术 | 4507篇 |
技术理论 | 1篇 |
综合类 | 4137篇 |
化学工业 | 18632篇 |
金属工艺 | 10425篇 |
机械仪表 | 3071篇 |
建筑科学 | 5186篇 |
矿业工程 | 947篇 |
能源动力 | 4591篇 |
轻工业 | 3777篇 |
水利工程 | 686篇 |
石油天然气 | 2240篇 |
武器工业 | 919篇 |
无线电 | 5005篇 |
一般工业技术 | 10951篇 |
冶金工业 | 2568篇 |
原子能技术 | 1086篇 |
自动化技术 | 1126篇 |
出版年
2024年 | 216篇 |
2023年 | 1421篇 |
2022年 | 1997篇 |
2021年 | 2602篇 |
2020年 | 2579篇 |
2019年 | 2395篇 |
2018年 | 2265篇 |
2017年 | 2754篇 |
2016年 | 2617篇 |
2015年 | 2677篇 |
2014年 | 3816篇 |
2013年 | 4350篇 |
2012年 | 4668篇 |
2011年 | 5050篇 |
2010年 | 3835篇 |
2009年 | 3936篇 |
2008年 | 3355篇 |
2007年 | 4224篇 |
2006年 | 4133篇 |
2005年 | 3318篇 |
2004年 | 2893篇 |
2003年 | 2313篇 |
2002年 | 2090篇 |
2001年 | 1797篇 |
2000年 | 1583篇 |
1999年 | 1215篇 |
1998年 | 1045篇 |
1997年 | 802篇 |
1996年 | 719篇 |
1995年 | 591篇 |
1994年 | 459篇 |
1993年 | 407篇 |
1992年 | 372篇 |
1991年 | 292篇 |
1990年 | 238篇 |
1989年 | 207篇 |
1988年 | 140篇 |
1987年 | 74篇 |
1986年 | 78篇 |
1985年 | 71篇 |
1984年 | 63篇 |
1983年 | 53篇 |
1982年 | 48篇 |
1981年 | 30篇 |
1980年 | 21篇 |
1979年 | 6篇 |
1976年 | 3篇 |
1975年 | 4篇 |
1959年 | 9篇 |
1951年 | 11篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
The photopolymerization of wood coatings under UV and visible light in industrial type conditions has been investigated. The inhibiting effect of the phenolic compounds found in wood extractives, especially quercetin, on the final properties of the coating (hardness, gel content) as well as the polymerization kinetics (rates, final conversion) has been discussed. Model clear‐coating formulations — based on an acrylate oligomer, a reactive diluent and a bis‐acylphosphine oxide as photo‐initiator — have been used. This article focuses on the influence of the nature of the acrylate oligomer (polyester, epoxy, polyurethane), the type of phenolic derivative (POHs) and the irradiation conditions (UV conveyor, Xe lamp). It appears that lead to through the strong inner‐filter effect in the presence of quercetin is responsible for the loss of all the observed properties. In order to mimic what happens at the wood–coating interface, the role of the diffusion of the phenolic derivatives have been also investigated and discussed. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3285–3298, 2007 相似文献
992.
Two zinc-rich powder coatings are applied onto phosphatised steel substrate and are studied using electrochemical impedance spectroscopy (EIS). Measurements are performed before (dry experiment) and during immersion in artificial sea water. Before immersion, EIS spectra show that percolation threshold is not attained for coating A, while coating B presents an effective percolation. In this latter case, and in order to account for the distribution of the zinc particles within the coating described as isolated, semi-isolated and percolant grains, a distributed transmission line model is proposed. When panels are immersed, the model is modified due to the electrolyte penetration through the coating, in particular with the introduction of an ionic resistance. However, it is shown that EIS spectra are not significantly modified when this ionic resistance is changed. 相似文献
993.
Fred J. Parker 《Journal of the American Ceramic Society》1990,73(4):929-932
The characterization and properties of ceramic composites containing the phases Al2 TiO5 , ZrTiO4 , and ZrO2 are described. The range of compositions investigated gives very low average thermal expansions (α24–1000°C as low as −2.0 × 10−6 °C−1 ) and excellent high-temperature stability. The low thermal expansions are apparently due to a combination of microcracking by the titanate phases and a contractive phase transformation by the ZrO2 . The crystal chemistry and microstructure of the product are processing dependent. Although the composites represent a complex microcracking system, the low thermal expansions and high-temperature stability make them potential candidates for commercial applications requiring thermal shock resistance. 相似文献
994.
995.
升温速率对油页岩热解特性的影响 总被引:5,自引:0,他引:5
采用热分析方法,在非等温条件下对茂名和桦甸的油页岩进行了热解试验研究。研究了从常温到900℃之间不同升温速率(10,20,40,50,100℃/m in)对油页岩热分解反应的影响以及油页岩的H/C,O/C,Cdaf,Vdaf等因素与(dw/dt)m ax之间的关系。根据试验数据建立了热解动力学模型,利用积分法求得表观活化能和频率因子等动力学参数。试验结果表明,油页岩热解可分为3个阶段,其中第2阶段(200—600℃)是热解反应最激烈的区域,挥发份几乎全部析出。而第3阶段是碳酸盐热解阶段,茂名油页岩由于碳酸盐含量低,此阶段变化甚微。 相似文献
996.
以聚二甲基硅氧烷为基体制备了一种耐高温涂层材料。探讨和分析了中空玻璃微珠和阻燃剂A的含量,不同溶剂、增塑剂的用量等因素对材料性能的影响。结果表明,随着中空玻璃微珠含量的增加,涂层材料的耐温性能有所提高;阻燃剂A的含量在20%以上时,阻燃效果非常明显;四氯化碳是单一溶剂的最佳选择;增塑剂用量一般控制在5%~8%。 相似文献
997.
Novel silica nanoboxes were prepared by controlled dealumination of Na-X and Ca-A type zeolites using ammonium hexafluorosilicate (AHFS). The silica-richer
the parent zeolite, the smaller the average pore size produced and the narrower the pore size distribution obtained. This
was due to the specific reactivity of the extracting agent with the zeolite framework aluminum atoms. High temperature calcination
of the dealuminated X-zeolite (ammonium form) resulted in mesoporous materials exhibiting an ink-bottle shape, a quite high
surface area (330 m2/g, no micropores), an average pore diameter of 4.5 nm with a quite narrow pore size distribution (± 1.0 nm) and finally,
a pore opening diameter of 3.9 nm. The latter was determined by using the nitrogen sorption isotherms (BET technique) and
related pore volume data. The sorption behavior also suggested the interconnecting character of the newly created nanoboxes. The periodicity of these nanoboxes throughout the mesoporous material was clearly shown by X-ray powder diffraction at very small angles.
These materials, herein called monomodal nanoboxes because of the absence of micropores in the structure, were also thermally stable. Incorporation of orthosilicate into the obtained silica nanoboxes, in accordance with the recently developed technique for
pore size engineering in zeolites, led to materials with smaller pore openings but having almost the same textural properties. Solid superacidic materials were prepared by incorporating a liquid superacid
(triflic acid or trifluoromethanesulfonic acid) into the silica nanoboxes using the wet impregnation technique. The maximum
triflic acid loading which did not significantly affect the mesoporous framework of the materials was 24 wt%. As a reference,
the maximum loading of less acidic sulfuric acid was slightly lower. All this showed the high chemical stability of the silica nanoboxes for supporting very acidic species. Temperature-programmed desorption using a combined DTA/TGA system
allowed the identification of the bound phases and some liquid phase of the loaded triflic acid. 相似文献
998.
999.
使用十八烷基三甲氧基硅烷(OTMS)对纳米SiO2进行表面疏水改性,将得到的改性纳米SiO2(OTMS-SiO2)添加到有机硅树脂(SI)中,然后采用两步法在聚乙烯(PE)薄膜表面固化制备了复合涂层SI/OTMS-SiO2.通过FTIR、1HNMR、29SiNMR、TGA对OTMS-SiO2及复合涂层进行了表征,采用接触角测量仪、SEM、AFM对复合涂层疏水特性和形貌进行了测试和观察,最后对复合涂层的耐磨性和附着力进行了分析.结果表明,SiO2表面成功引入了OTMS,且OTMS-SiO2均匀附着在硅树脂涂层上,增加了表面粗糙度,得到了PE基固化超疏水复合涂层.当OTMS-SiO2添加量为正己烷质量的8%时,制得的复合涂层的水接触角为154°,滚动角为7°,并具有良好的耐磨性,其附着力可达4A等级. 相似文献
1000.
镍/纳米二氧化硅纳米复合镀层耐腐蚀性能的研究 总被引:1,自引:0,他引:1
制备了纳米氧化硅镍复合镀层材料,并利用静态浸泡法对纯镍镀层和由镀液中不同微粒含量制备的复合镀层样品的耐蚀性能进行了研究,讨论镀液中纳米微粒含量对镀层抗蚀性能的影响。并用扫描电镜观察镀层的表面形貌。 相似文献